Not sure if it will work since the certificates file is not present on MacOS AFAICT but it is needed for GTK 4 so 🤷♀️.
Also clean up the expression and correct license.
continuation of #109595
pkgconfig was aliased in 2018, however, it remained in
all-packages.nix due to its wide usage. This cleans
up the remaining references to pkgs.pkgsconfig and
moves the entry to aliases.nix.
python3Packages.pkgconfig remained unchanged because
it's the canonical name of the upstream package
on pypi.
